Study of Voltammetric Determination of Carcinogenic 1-Nitropyrene and 1-Aminopyrene Using a Glassy Carbon Paste Electrode

نویسندگان

  • Jirí Barek
  • Alexandr Muck
  • Joseph Wang
  • Jirí Zima
چکیده

Linear scan voltammetry (LSV), differential pulse voltammetry (DPV) and voltammetry with adsorptive accumulation (AAV) at a glassy carbon paste electrode (GCPE) based on mixing glassy carbon spherical microparticles with an organic pasting liquid were used for the determination of trace amounts of carcinogenic 1-nitropyrene (1NP) (the limit of determination around 2.10 mol L for LSV and 2.10 mol L for DPV) and 1-aminopyrene (1-AP) (the limit of determination around 3.10 mol L for LSV, 1.10 mol L for DPV and 1.10 mol L for AAV) using a Britton-Robinson buffer – methanol mixture as a base electrolyte. The main advantage of this new type of electrode is its full compatibility with media containing a high amount of organic solvent (methanol, acetonitrile)

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Simultaneous determination of dopamine and uric acid using a glassy carbon paste electrode modified with copper- para red complex

A simple approach based on cyclic voltammetry (CV) was developed for the simultaneous determination of dopamine (DA) and uric acid (UA) in the presence of ascorbic acid (AA) using a modified glassy carbon paste electrode (GCPE). In the present study, analytical parameters were optimized and electrochemical performance of modified electrode was investigated. The calibration curves were obtained ...

متن کامل

Voltammetric Determination of Penicillamine Using a Carbon Paste Electrode Modified with Multiwall Carbon Nanotubes In the Presence of Methyldopa as a Mediator

A multiwall carbon nanotubes-modified carbon paste electrode (MWCNTs/MCPE) wasfabricated and used to study the electrooxidation of penicillamine (PA) by electrochemicalmethods in the presence of methyldopa (MDOP) as a homogeneous mediator. Theelectrochemical oxidation of PA on the new sensor has been carefully studied. The kineticparameters such as electron transfer coefficient, α, and catalyti...

متن کامل

Silica Nanoparticles Modified Carbon Paste Electrode as a Voltammetric Sensor for Determination of Diclofenac

The present study describes the use of a new carbon paste electrode modified by means of Silica nanoparticles prepared by a simple and rapid procedure for the determination of sodium diclofenac (DCF). Moreover, the present study focuses on the characterization of electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) of the prepared Silica NPs-CPE. In this work, The...

متن کامل

Voltammetric Determination of Penicillamine Using a Carbon Paste Electrode Modified with Multiwall Carbon Nanotubes In the Presence of Methyldopa as a Mediator

A multiwall carbon nanotubes-modified carbon paste electrode (MWCNTs/MCPE) wasfabricated and used to study the electrooxidation of penicillamine (PA) by electrochemicalmethods in the presence of methyldopa (MDOP) as a homogeneous mediator. Theelectrochemical oxidation of PA on the new sensor has been carefully studied. The kineticparameters such as electron transfer coefficient, α, and catalyti...

متن کامل

Voltammetric Determination of Tryptophan Using a Carbon Paste Electrode Modified with Magnesium Core Shell Nanocomposite and Ionic Liquids

A novel carbon paste electrode modified with ionic liquid (n-hexyl-3-methylimidazolium hexafluoro phosphate) and magnetic core-shell manganese ferrite nanoparticles (MCSILCPE) was fabricated. The electrochemical study of the modified electrode, as well as its efficiency for electro-oxidation of tryptophan, is described. Cyclic voltammetry (CV), choronoamperometry (CHA) and square wave voltammet...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 4  شماره 

صفحات  -

تاریخ انتشار 2004